Triphosphane
From Wikipedia, the free encyclopedia
(Redirected from Triphosphene)
See also: triphos
|
|||
| Names | |||
|---|---|---|---|
| Systematic IUPAC name
Triphosphane[2]
|
|||
| Other names
Triphosphine[1]
|
|||
| Identifiers | |||
13597-70-1  |
|||
| 3D model (Jmol) | Interactive image | ||
| ChEBI | CHEBI:35893  |
||
| ChemSpider | 123032 |
||
| PubChem | 139510 | ||
|
|||
|
|||
| Properties | |||
| P 3H 5 |
|||
| Molar mass | 97.96099 g·mol−1 | ||
| Appearance | Colourless gas | ||
| Related compounds | |||
|
Other anions
|
triazane | ||
|
Related Binary phosphanes
|
phosphane diphosphane |
||
|
Related compounds
|
triazene | ||
|
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
|
|||
 verify (what is ?) |
|||
| Infobox references | |||
Triphosphane (IUPAC systematic name) or triphosphine is an inorganic compound having the chemical formula HP(PH2)2. It can be generated from diphosphine but is highly unstable at room temperature:[3]
- 2 P2H4 → P3H5 + PH3
Samples to date have been contaminated with P2H4 and P4H6 (both branched and linear isomers).[4]
References[edit]
- ^ "Triphosphine". NIST Chemistry WebBook. USA: National Institute of Standards and Technology. Retrieved 27 September 2011.
- ^ "triphosphane (CHEBI:35893)". Chemical Entities of Biological Interest (ChEBI). UK: European Bioinformatics Institute. 7 June 2006. Main. Retrieved 27 September 2011.
- ^ Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. ISBN 0-08-037941-9.
- ^ Marianne Baudler, Klaus Glinka (1993). "Monocyclic and polycyclic phosphines". Chem. Rev. 93: 1623–1667. doi:10.1021/cr00020a010.
External links[edit]
| Alkali metal hydrides |
 Lithium hydride, LiH ionic metal hydride   Beryllium hydride Left (gas phase): BeH2 covalent metal hydride Right: (BeH2)n (solid phase) polymeric metal hydride   Borane and diborane Left: BH3 (special conditions), covalent metalloid hydride Right: B2H6 (standard conditions), dimeric metalloid hydride  Methane, CH4 covalent nonmetal hydride  Ammonia, NH3 covalent nonmetal hydride  Water, H2O covalent nonmetal hydride  Hydrogen fluoride, HF covalent nonmetal hydride |
||||||||||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| Alkaline earth hydrides |
|
||||||||||||||||||
| Group 13 hydrides |
|
||||||||||||||||||
| Group 14 hydrides |
|
||||||||||||||||||
| Pnictogen hydrides |
|
||||||||||||||||||
| Hydrogen chalcogenides |
|
||||||||||||||||||
| Hydrogen halides | |||||||||||||||||||
| Transition metal hydrides | |||||||||||||||||||
| Lanthanide hydrides |
|
||||||||||||||||||
| Actinide hydrides |
|
||||||||||||||||||
